Contribution of dissolved organic matter to submicron water- soluble organic aerosols in the marine boundary layer over the eastern equatorial Pacific

Stable carbon isotopic compositions of water-soluble organic carbon (WSOC) and organic molecular markers were measured to investigate the relative contributions of the sea-surface sources to the water-soluble 15 fraction of submicron organic aerosols collected over the eastern equatorial Pacific during the Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOCs (TORERO)/KA-12-01 cruise. On average, the water-soluble organic fraction of the total carbon (TC) mass in submicron aerosols was ~30–35% in the oceans with the low chlorophyll a (Chl a) concentrations, whereas it was ~60% in the high Chl a regions. The average stable carbon isotope ratio of WSOC (δCWSOC) was −19.8 ± 2.0‰, which was systematically higher 20 than that of TC (δCTC) (−21.8 ± 1.4‰). We found that in the oceans with both high and low Chl a concentrations, the δCWSOC was close to the typical values of δ13C for dissolved organic carbon (DOC), ranging from −22‰ to −20‰ in surface seawater of tropical Pacific oceans. This suggests an enrichment of marine biological products in WSOC aerosols in the study region regardless of the oceanic area. In particular, enhanced levels of WSOC and biogenic organic marker compounds together with high values of WSOC/TC (~60%) and 25 δCWSOC were observed over upwelling areas and phytoplankton blooms, which was attributed to planktonic tissues being more enriched in δ13C. The δ13C analysis estimated that on average, marine sources contribute ~90 ± 25% of the aerosol carbon, indicating the predominance of marine-derived carbon in the submicron WSOC. This conclusion is supported by Lagrangian trajectory analysis, which suggests that the majority of the sampling points on the ship had been exposed to marine boundary layer air for more than 80% of the time during the 30 previous 7 days. The combined analysis of the δ13C and monosaccharides, such as glucose and fructose, demonstrated that DOC concentration was closely correlated with the concentration levels of submicron WSOC across the study region regardless of the oceanic area. The result implies that DOC may characterize background organic aerosols in the MBL over the study region.